The Gnumeric spreadsheet application comes with a command line utility called ssconvert that can convert between a variety of spreadsheet formats:
$ ssconvert Book1.xlsx newfile.csv
Using exporter Gnumeric_stf:stf_csv
$ cat newfile.csv
Foo,Bar,Baz
1,2,3
123.6,7.89,
2012/05/14,,
The,last,Line
To install on Ubuntu:
apt-get install gnumeric
To install on Mac:
brew install gnumeric
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