This one's pretty self-explanatory, but there's not much you to my knowledge can do about the error you're getting:
Peer certificate CN=`server12.thulo.com' did not match expected CN=`smtppro.zoho.com'
This indicates a certificate mismatch issue - the SMTP certificate verification for the TLS connection did not match what was expected and therefore you have an "Invalid Certificate" problem - in Firefox or Chrome this would be "The certificate does not match the domain/url".
This is an issue with the SMTP side of things, on the remote servers you're connecting to, and it may be something you have to talk to Zoho about for properly configuring this; if Perfex CRM has an option in its SMTP settings to ignore invalid certificates then that's your workaround, but it's a very insecure workaround.
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