you can do it this way:
In [84]: df
Out[84]:
A B
0 some value [[L1, L2]]
1 another value [[L3, L4, L5]]
In [85]: (df['B'].apply(lambda x: pd.Series(x[0]))
....: .stack()
....: .reset_index(level=1, drop=True)
....: .to_frame('B')
....: .join(df[['A']], how='left')
....: )
Out[85]:
B A
0 L1 some value
0 L2 some value
1 L3 another value
1 L4 another value
1 L5 another value
UPDATE: a more generic solution
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